Fenton 试剂法预处理高氯化工废水的研究

采用Fenton试剂预处理高氯化工废水，考察了主要影响因素，确定了最佳工艺参数．结果表明，在pH值为4，H202投加量325mmol，FeSO4投加量20．8mmol，反应时间90min的条件下处理250mL废水。COD去除率达到64％以上，B／C值由0．016提高到0．35，水质得到明显改善，有利于后续生化处理．     

基于集聚优势的园区型循环经济产业链构建研究——以洛阳国家级高新技术开发区为例

以洛阳国家级高新技术开发区为假设载体,通过对洛阳高新区构建循环经济产业链的优劣势分析,阐述了洛阳高新区构建循环经济产业链的基本原则,构建了洛阳高新区总体循环经济产业链和循环经济分产业链,并从区内循环经济型企业建设、建立健全区内循环经济发展规划和管理制度、严格实行企业准入制度、加强发展循环经济产业链的监管以及科技支撑体系建设等方面对洛阳高新区循环经济产业链的构建提出了政策支持措施。     

中国近代教育家、物理学家——孙国封

孙国封(1890—1936)先生是中国近代教育家、物理学家,是中国第一届在国内培养的物理学毕业生。他参与筹建了东北地区第一所高水平大学——东北大学,并担任理工院院长,复任教育部督学、北平大学工学院院长,而这两所工学院于1938年与西北联大工学院合组为西北工学院,从而奠定了我国东北、西北工程技术教育的基础。通过研究中国本土培养的第一代物理学家,在一定程度上,可以折射出中国物理学发生与发展的历史轨迹,进而引发人们对中国物理学史的思考。     

Structural phase transition and metallization in compressed SrC_2

The structural, dynamical, and electronic properties of compressed Sr C2 were systematically investigated up to 200 GPa by using ab initio method. Three new phases are obtained by means of evolutionary algorithm. The confirmed most stable structure has C2/c symmetry at zero pressure, which transforms into an orthorhombic Cmcm phase at 4.5 GPa, followed by another orthorhombic Immm phase, which is stabilized at wide pressure range of 21.5–123.5 GPa, and then transformed into Mg B2-type phase（space group, P6/mmm）. Although Sr C2 has similar structural transformation to that of compressed Ca C2, Sr C2 holds small electron–phonon coupling,which leads to its low superconducting critical temperature（only 1.8 K）.     

Compression behavior of Sm）2Ti2O7-pyrochlore up to 50 GPa：single-crystal X-ray diffraction and density functional theory calculations

Single-crystal X-ray diffraction at pressures up to 50 GPa has been employed to study the compression behavior of Sm2Ti2O7-pyrochlore. In contrast to earlier reports, we observed no pressure-induced amorphization or pressure-induced anion disorder up to 50 GPa. The experimental study has been complemented by density functional theory-based calculations. A combination of the theoretical and experimental data yields a bulk modulus of 185 GPa, significantly higher than a value which had been reported earlier. In comparison to earlier work, the current study provides more reliable data due to the use of neon as a pressure medium, which provides a more hydrostatic pressure than the aluminum, which had been employed as a pressure medium in the earlier studies. An analysis of the compressibility of Al2B2O7 pyrochlores shows an approximately linear dependence of the bulk modulus on the unit cell volume.     

Synthesis of Ta C and Ta_2C from tantalum and graphite in the laser-heated diamond anvil cell

The pressure dependence of the onset of the formation of Ta C and Ta2 C from the elements has been investigated by in situ X-ray diffraction and pyrometry.Ta C has been synthesized by the reaction of Ta and graphite at pressures between 8.6 and 14.3 GPa and at temperatures up to 2,300 K using a laser-heated diamond anvil cell. The products were characterized by X-ray diffraction. Ta and graphite begin to react around 1,100 K at ambient pressure conditions, and the reaction temperature increases with increasing pressure. A linear extrapolation of these data is consistent with recent observations of the formation of Ta C at 90 GPa and 3,600 K. We show that diffusion of carbon into tantalum significantly changes the lattice parameter of up to 2 % in the pressure range of up to19 GPa. In some experiments, Ta2 C was formed concomitantly. The experimentally determined bulk modulus of Ta2 C is B0;exp：= 286（5） GPa. Other tantalum carbide phases were not observed.     

Retrieval of column-averaged volume mixing ratio of CO2 with ground-based high spectral resolution solar absorption

The total column-averaged volume mixing ratio of atmospheric carbon dioxide （Xco2） has been retrieved with high spectral resolution solar absorption data obtained from ground-based Fourier transform spectrometer （FTS） measurements at Xichong, a coastal site in the district of Shenzhen in southern China. Based on differential optical absorption spectroscopy （DOAS） theory, the Xco2 was retrieved by finding the best match of observed high spectral resolution solar absorption data and monochromatic radia- tion transfer model calculations. The averaged Xco2 in the whole observation period was about 394.9 ppm. The uncertainty of the retrieval was estimated to be 2.0 ppm （0.51%） by comparing retrievals at two bands. The preliminary results show that Xc% retrieved by this method can be used to validate satellite remote sensing of Xco2.     

高效液相色谱同时测定何首乌中大黄酸、大黄素和大黄酚的含量

采用高效液相色谱法建立了同时测定何首乌中大黄酸、大黄素、大黄酚三种蒽醌类化合物的方法,样品采用超声波法提取,色谱柱为Phenomenex C18(250mm×4.6mm,5μm);流动相为甲醇-0.4%醋酸水溶液(80∶20);流速0.80mL/min;紫外检测波长254nm;柱温为35℃.结果:该方法对大黄酸、大黄素和大黄酚分别在0.0001~12.50μg/mL、0.0002~25.00μg/mL、0.00018~22.50μg/mL范围内线性关系良好,相关系数(r)均大于0.9999,定性检测限(S/N=3)依次是:0.0703ng/mL、0.0282ng/mL、0.0871ng/mL;样品回收率为88.39%~107.2%.结论:本法操作简单快速、定量准确、灵敏度高、成本低,为何首乌中蒽醌类化合物的检测分离及含量测定提供了一个有效的科学方法.     

DCQD:一种物联网高性能数据采集平台的设计与实现

在物联网环境中,大量的传感器产生了海量的数据.这些数据通常都需要写入到数据库中来实现数据的分析与应用.当这些物联网海量传感器数据插入到数据库中的时候,会在存储系统中产生严重的小数据同步写性能瓶颈.针对此问题,本文设计了一种高性能数据库磁盘缓冲队列DCQD(Disk Cache Queue for Database).DCQD在保证物联网采集数据同步写入磁盘,确保不丢失数据的基础上,可以显著优化海量数据插入到数据库中的性能.实验表明,DCQD在物联网应用环境中,可以显著地提高数据采集系统的性能.     

高凝油田不同驱替温度下孔渗变化规律及对相渗曲线特征参数的影响研究

高凝油藏(原油凝固点在40℃以上,含蜡量高的油藏)在开采过程中,由于黏度增加、析蜡等现象,将使得储层流动性变差,影响开发效果,但目前国内外针对高凝油的流变性及驱替过程中的储层物性变化规律的定性研究较少。根据海外某高凝油田A的流变性试验和驱替试验结果,分析了高凝油随温度降低所产生的黏度增加以及蜡的析出对孔隙度、渗透率和驱替效果的影响。重点分析了黏度、孔隙度、渗透率随温度变化的规律,并提出一项新的、可同时表征储层物性与流体性质的储层特征参数γ。分析了不同温度、不同γ下的相渗参数及相关关系。研究结果对类似高凝油田开发具有一定的参考意义。